Coupled (H, M) substitutions in forsterite     

Feiwu Zhang  Kate Wright 《Geochimica et cosmochimica acta》2010,74(20):5958-5965

Coupled substitutions involving hydrogen plus trivalent elements (Al, Eu, Fe, Ga, Gd, Lu, Mn, Nd, Pu, Sc, Y and Yb) in forsterite (Mg₂SiO₄) are studied using atomistic simulation methods. Incorporation of hydrogen is energetically favourable when included in the forsterite lattice as hydroxyl groups (OH⁻) at O3 sites while the trivalent cations replace either magnesium or silicon. Our calculations show a strong dependence on the ionic radius of the impurity species and some variation with pressure. There are also significant structural distortions around the impurity defects. At low pressure (0 GPa), the smaller trivalent cations, (e.g. Al, Fe, Mn and Ga) substitute into forsterite by replacing Si as: . The larger trivalent cations (e.g. Eu, Gd, Lu, Nd, Pu, Y and Yb) however, replace Mg at the M2 site coupled with an Mg1 vacancy as described by . At 12 GPa, the large cations are more stable at Mg1 relative to Mg2, but both are predicted to be less stable than configurations associated with Si vacancies. The trivalent ionic radius has a significant effect on the H incorporation mechanism, however, the high formation energy of Si vacancies suggests that the presence of H in forsterite could inhibit incorporation of these elements, particularly at high pressure.  相似文献   

Mapping rates associated with polygons     

Noel Cressie  Hal S. Stern  Deanne Reber Wright 《Journal of Geographical Systems》2000,2(1):61-69

Suppose that geographic data under investigation are rates associated with polygons. For example, disease incidence, mortality, and census undercount data may be displayed as rates. Spatial analysis of data of this sort can be handled very naturally through Bayesian hierarchical statistical modeling, where there is a measurement process at the first level, an explanatory process at the second level, and a prior probability distribution on unknowns at the third level. In our paper, we shall feature epidemiological data, specifically disease-incidence rates, and the “polygons” referred to in the title are typically states or counties.  相似文献   

Introduction to the reconstruction of the late-glacial and early-Holocene aquatic ecosystems at Kråkenes Lake, Norway     

Hilary H. Birks  Herbert E. Wright 《Journal of Paleolimnology》2000,23(1):1-5

  相似文献   

Lake Gościąż, central Poland. M. Ralska-Jaseiwiczowa, T. Goslar, T. Medeyska, L. Starkel     

H.E. Jr. Wright 《Journal of Paleolimnology》2000,24(2):237-240

  相似文献   

High-latitude HF Doppler observations of ULF waves: 2. Waves with small spatial scale sizes     

D. M. Wright  T. K. Yeoman 《Annales Geophysicae》1999,17(7):868-876

The DOPE (Doppler Pulsation Experiment) HF Doppler sounder located near Tromsø, Norway (geographic: 69.6°N 19.2°E; L = 6.3) is deployed to observe signatures, in the high-latitude ionosphere, of magnetospheric ULF waves. A type of wave has been identified which exhibits no simultaneous ground magnetic signature. They can be subdivided into two classes which occur in the dawn and dusk local time sectors respectively. They generally have frequencies greater than the resonance fundamentals of local field lines. It is suggested that these may be the signatures of high-m ULF waves where the ground magnetic signature has been strongly attenuated as a result of the scale size of the waves. The dawn population demonstrate similarities to a type of magnetospheric wave known as giant (Pg) pulsations which tend to be resonant at higher harmonics on magnetic field lines. In contrast, the waves occurring in the dusk sector are believed to be related to the storm-time Pc5s previously reported in VHF radar data. Dst measurements support these observations by indicating that the dawn and dusk classes of waves occur respectively during geomagnetically quiet and more active intervals.  相似文献   

Fabrics,facies control and diagenesis of lacustrine ooids and associated grains from the Upper Triassic,southwest England     

P. G. Milroy  V. P. Wright 《Geological Journal》2002,37(1):35-53

Petrographic analysis of ooids from the Upper Triassic (Mercia Mudstone Group) of southwest England provides an opportunity to assess in detail the origins, transport pathways and diagenesis of an ancient oolite. The Clevedon Oolite is dolomitized and contains a variety of dissolved ooids (oomoulds) and associated grains. The oomoulds occur in well‐sorted, planar and cross‐stratified grainstones, packstones, sandstones and conglomerates associated with shoreface, intershoal, foreshore, beachrock and littoral strandplain deposits. The ooids grew in suspension in the shoreface zone and developed a radial aragonite microstructure. The ooids grew to 0.80 mm in diameter, after which they fractured or ceased growing. Broken grains deposited on or near mobile shoals were rapidly recoated, while other grains, deposited in less agitated, intershoal and lower foreshore areas, were micritized or microbially bound into grapestone aggregates. Locally peloids, intraclasts, quartz grains and micritized grains from intershoal areas supplied nuclei for ooids on nearby shoals. Grains deposited in foreshore areas were rapidly cemented into beachrock and reworked into conglomerates. Soon after deposition, the ooids were subjected to widespread aragonite dissolution followed by dolomitization. The lack of pre‐dolomitization calcite, together with the abundance of early (pre‐compaction) dolospar cements and fabric‐selective dolomitization of micritic fabrics, suggest aragonite dissolution by dolomitizing fluids. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献